While it might look like a random definition, the cross product is the "best" way to find a vector perpendicular to two vectors. Geometrically, the cross product looks like the following:
The direction of v×w is determined by the right-hand rule, like the axes. If you look at the picture, you'll see that order matters! v×w and w×v point in opposite directions, and you can check that the directions are consistent with the right-hand rule.
Algebraically, you can calculate the cross product with the following determinant formula:
Notice that there is an additional minus sign when calculating the j^-coordinate. Lastly, on #6 of this week's worksheet, you will show that the length of v×w is the area of parallelogram spanned by v and w:
The area of the parallelogram is the height (∥w∥sinθ) times the base length (∥v∥), which is what #6 tells you:
∥v×w∥=∥v∥∥w∥sinθ,
where θ is the angle between v and w measured in the interval [0,π] (or [0∘,180∘] in degrees).
Triple Product
I made a GeoGebra graph to help show why u⋅(v×w)=0 tells you that u,v,w are coplanar.