(701, #57) A molecule of methane,
, is structured with four
hydrogen atoms at the vertices of a regular tetrahedron and the
carbon atom at the centroid. The bond angle is the angle formed
by H-C-H combination; it is the angle between the lines that join
the carbon atom to two of the hydrogen atoms. Show that the bond
angle is about
.
[Hint: Take the vertices of the tetrahedron to be the points (1,0,0),
(0,1,0), (0,0,1), and (1,1,1) as shown in the figure. Then the centroid is
.
Solution: Let v be the vector from the centroid to the point (0,1,0);
let w be the vector from the centroid to the point (0,0,1). Then
Thus if
is the angle between v and w then
Ans:
by: gm